2-methyl-3-phenylpropanol
Base Information
- Chemical Name: 2-methyl-3-phenylpropanol
- CAS No.: 7384-80-7
Top Quality Chinese Factory supply 7384-80-7 2-methyl-3-phenylpropanol
- Molecular Formula: C10H14O
- Molecular Weight: 150.221
- Vapor Pressure: 0.0147mmHg at 25°C
- Melting Point: 84 °C
- Boiling Point: 246.1°C at 760 mmHg
- PKA: 15.03±0.10(Predicted)
- Flash Point: 106.2°C
- PSA: 20.23000
- Density: 0.98g/cm3
- LogP: 1.85750
2-methyl-3-phenylpropanol(Cas 7384-80-7) Usage
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Synthesis Reference(s) |
Canadian Journal of Chemistry, 57, p. 2522, 1979 DOI: 10.1139/v79-404 |
InChI:InChI=1/C10H14O/c1-9(8-11)7-10-5-3-2-4-6-10/h2-6,9,11H,7-8H2,1H3
7384-80-7 Relevant articles
Highly efficient NHC-iridium-catalyzed β-methylation of alcohols with methanol at low catalyst loadings
Lu, Zeye,Zheng, Qingshu,Zeng, Guangkuo,Kuang, Yunyan,Clark, James H.,Tu, Tao
, p. 1361 - 1366 (2021/06/30)
The methylation of alcohols is of great ...
Your mother was right, washing matters: An alkyne-analog of ibuprofen reveals unwanted reactivity of aromatic compounds with proteins during copper-catalyzed click chemistry
Cutolo, Giuliano,Pratt, Matthew R.,Shankar, Sahiti N.
supporting information, (2021/07/19)
Bioorthogonal chemistry, in particular t...
Deep eutectic solvents as H2-sources for Ru(II)-catalyzed transfer hydrogenation of carbonyl compounds under mild conditions
Cavallo, Marzia,Arnodo, Davide,Mannu, Alberto,Blangetti, Marco,Prandi, Cristina,Baratta, Walter,Baldino, Salvatore
supporting information, (2021/02/22)
The employment of easily affordable ruth...
A Water/Toluene Biphasic Medium Improves Yields and Deuterium Incorporation into Alcohols in the Transfer Hydrogenation of Aldehydes
Ruiz-Casta?eda, Margarita,Santos, Lucía,Manzano, Blanca R.,Espino, Gustavo,Jalón, Félix A.
, p. 1358 - 1372 (2021/03/16)
Deuterium labeling is an interesting pro...
7384-80-7 Process route
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300-57-2,57807-91-7
allylbenzene
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-
201230-82-2
carbon monoxide
-
-
103-65-1
phenylpropane
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-
3360-41-6
4-phenyl-butan-1-ol
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-
2035-94-1,89104-46-1
2-phenylbutan-1-ol
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22436-06-2,77943-96-5,78964-61-1,7384-80-7
2-methyl-3-phenylpropanol
| Conditions | Yield |
|---|---|
|
With
dodecacarbonyl-triangulo-triruthenium; 2-(dicyclohexylphosphino)-1-methyl-1H-imidazole; water; hydrogen; lithium chloride;
In
1-methyl-pyrrolidin-2-one;
at 130 ℃;
for 20h;
under 60 Torr;
regioselective reaction;
Autoclave;
|
57%
7% 25% 9 %Chromat. |
-
-
873-66-5
1-propenylbenzene
-
-
201230-82-2
carbon monoxide
-
-
3360-41-6
4-phenyl-butan-1-ol
-
-
2035-94-1,89104-46-1
2-phenylbutan-1-ol
-
-
22436-06-2,77943-96-5,78964-61-1,7384-80-7
2-methyl-3-phenylpropanol
| Conditions | Yield |
|---|---|
|
With
[bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); 2-(dicyclohexylphosphanyl)-1-(2-methoxyphenyl)-1H-imidazole; hydrogen;
In
toluene;
at 160 ℃;
for 24h;
under 37503.8 Torr;
Overall yield = 88 %Chromat.; regioselective reaction;
Autoclave;
Inert atmosphere;
|
39%
19% |
7384-80-7 Upstream products
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5445-77-2
(2S)-2-methyl-3-phenylpropanal
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1009-67-2
2-methyl-3-phenylpropionic acid
-
100-39-0
benzyl bromide
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155956-27-7
(2'R,3'R,5R)-(-)-1-(3'-hydroxy-2'-methyl-3'-phenyl-1'-oxopropyl)-3,3,5-trimethyl-2-pyrrolidinone
7384-80-7 Downstream products
-
111539-83-4
Toluene-4-sulfonic acid (S)-2-methyl-3-phenyl-propyl ester
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5445-77-2
(2S)-2-methyl-3-phenylpropanal
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67180-08-9
(2S,3S)-threo-3-Methyl-4-phenyl-2-butanol
-
2550-27-8
(3S)-3-methyl-4-phenylbutan-2-one
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