Ethyl 4-methoxybenzoate
Base Information
- Chemical Name:Ethyl 4-methoxybenzoate
- CAS No.:94-30-4
Factory Supply Industrial Grade Ethyl 4-methoxybenzoate 94-30-4 with Best Price
- Molecular Formula:C10H12O3
- Molecular Weight:180.203
- Appearance/Colour:clear yellow liquid
- Vapor Pressure:0.000846mmHg at 25°C
- Melting Point:7-8 °C(lit.)
- Refractive Index:n20/D 1.524(lit.)
- Boiling Point:266.58 °C at 760 mmHg
- Flash Point:106.102 °C
- PSA：35.53000
- Density:1.074 g/cm3
- LogP:1.87190
Ethyl 4-methoxybenzoate(Cas 94-30-4) Usage
|
Preparation |
By esterification of anisic acid with ethanol in the presence of an acid catalyst. |
|
Safety Profile |
Moderately toxic by ingestion. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. |
|
Production Methods |
Produced through the esterification of p-methoxybenzoic acid and ethanol under acidic catalysis. |
|
Taste threshold values |
Taste characteristics at 30 ppm: anise, sweet, fruity, licorice, grape and cherry-like. |
InChI:InChI=1/C10H12O3/c1-3-7-6-8(13-2)4-5-9(7)10(11)12/h4-6H,3H2,1-2H3,(H,11,12)/p-1
94-30-4 Relevant articles
Mechanistic insight into the synergistic Cu/Pd-catalyzed carbonylation of aryl iodides using alcohols and dioxygen as the carbonyl source
Li, Junxuan,Zhou, Jinlei,Wang, Yumei,Yu, Yue,Liu, Qiang,Yang, Tilong,Chen, Huoji,Cao, Hua
, p. 68 - 74 (2021/11/16)
Pd-catalyzed carbonylation, as an effici...
Alternative method for the synthesis of triazenes from aryl diazonium salts
Abrams
, (2021/05/10)
An alternative mild method for access to...
Electro-Oxidative Selective Esterification of Methylarenes and Benzaldehydes
Yu, Congjun,?zkaya, Bünyamin,Patureau, Frederic W.
supporting information, p. 3682 - 3687 (2021/02/01)
A mild and green electro-oxidative proto...
Copper-mediated simple and direct aerobic oxidative esterification of arylacetonitriles with alcohols/phenols
Dong, Jianyu,Chen, Xiuling,Ji, Fangyan,Liu, Lixin,Su, Lebin,Mo, Min,Tang, Jian-Sheng,Zhou, Yongbo
, (2020/10/20)
A simple and direct aerobic oxidative es...
94-30-4 Process route
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-
64-17-5
ethanol
-
-
6310-14-1
4-methoxyacetophenone hydrazone
-
-
94-30-4
ethyl 4-methoxybenzoate
-
-
100-06-1
1-(4-methoxyphenyl)ethanone
| Conditions | Yield |
|---|---|
|
With
N,N'-bis(salicylidene)ethylenediaminatocobalt(III) hydroxide; oxygen;
for 1h;
Ambient temperature;
|
60% 30% |
-
-
64-17-5
ethanol
-
-
100-07-2
4-methoxy-benzoyl chloride
-
-
94-30-4
ethyl 4-methoxybenzoate
-
-
100-09-4
4-methoxybenzoic acid
| Conditions | Yield |
|---|---|
|
With
water;
at 25 ℃;
Rate constant;
Product distribution;
Mechanism;
solvolysis examined; var. solvents and ratio of ones;;
|
|
|
In
water;
at -20 - 25 ℃;
Kinetics;
Thermodynamic data;
ΔH<*>(excit.), ΔS<*>(excit.);
|
|
|
With
water;
In
acetonitrile;
at 25 ℃;
Further Variations:;
Temperatures;
Product distribution;
|
94-30-4 Upstream products
-
64-17-5
ethanol
-
108791-37-3
2,2-dichloro-1-(4-methoxyphenyl)-2-phenylethanone
-
141-52-6
sodium ethanolate
-
119-52-8
4,4'-dimethoxybenzoin
94-30-4 Downstream products
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17403-82-6
3-(p-methoxyphenyl)-2-pentene
-
101273-93-2
2-(benzo[d]thiazol-2-yl)-1-(4-methoxyphenyl)ethan-1-one
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1712-69-2
1-isopropenyl-4-methoxybenzene
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7428-99-1
2-(4-methoxyphenyl)propan-2-ol